2 Which of the Following Can Be Bidentate Ligands

This reaction shows good functional group compatibility and can serve as a powerful synthetic tool for gram-scale synthesis and late-stage C-N borylation of complex. Another commonly used palladium source is PdPPh 3 2 Cl 2 but complexes containing bidentate phosphine ligands such as PdCl 2 PdCl 2 and PddppfCl 2 have also been used.


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The appropriate choice of a nickel catalyst NiCOD 2 ICyHCl as a ligand and the use of 2-ethoxyethanol as the cosolvent enables a highly efficient C-N bond borylative cleavage of sp 2 and sp 3 C-N bonds.

. The drawback to such catalysts is the need for high loadings of palladium up to 5 mol along with a larger amount of a copper co-catalyst.


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